Castillian Resources Corp. (TSX VENTURE:CT)(OTCQX:CTIIF) ("Castillian" or the
"Company") is pleased to announce an update to its National Instrument 43-101
("NI 43-101") Mineral Resource estimate for the Hope Brook Gold Project in
southwestern Newfoundland which was previously released on February 14, 2012.
This update incorporates results from the 4,549 metre, 15 hole, Phase I diamond
drilling program. This drilling confirmed major pillars in the Mine Zone area,
confirmed locations of underground workings in the former mine and further
extended the Southwest Extension target zone (see press releases dated June 5,
2012 and June 25, 2012). The updated mineral resource estimate is presented in
Table 1 below. 




----------------------------------------------------------------------------
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           Table 1: Hope Brook Gold Project as at October 1, 2012           
                    (see page 3 for Notes on Methodology)                   
----------------------------------------------------------------------------
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            Within constraining    Below constraining                       
                   shell                 shell                              
           @ 0.50 g Au/t cut-off  @ 2.0 g Au/t cut-off         Total        
----------------------------------------------------------------------------
----------------------------------------------------------------------------
            Tonnes                Tonnes                Tonnes              
            (Mill-  Grade     Au  (Mill-   Gold   Gold  (Mill-  Grade     Au
Category     ions)  (g/t)  (kOz)   ions)  (g/t)  (kOz)   ions)  (g/t)  (kOz)
----------------------------------------------------------------------------
Indicated     10.6   1.24    422     1.7   2.99    168    12.4   1.48    590
----------------------------------------------------------------------------
Inferred       6.5   1.91    397     2.0   2.62    151     8.2   2.07    548
----------------------------------------------------------------------------
----------------------------------------------------------------------------



As shown in Table 2 below, total Indicated Mineral Resources increased 102% to
590,000 ounces of gold from the February 14, 2012 estimate. Total Inferred
Mineral Resources had a modest decrease of 26% to 548,000 ounces of gold, which
is the result of the successful conversion of Inferred to Indicated Mineral
Resources through the 2012 diamond drilling program. Within the constraining
shell, there was a significant increase in grade in both the Indicated and
Inferred Mineral Resources, reflecting the confirmation of grade in pillars and
location of underground workings.




----------------------------------------------------------------------------
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     Table 2: Comparison to February 14, 2012 Mineral Resource Estimate     
----------------------------------------------------------------------------
----------------------------------------------------------------------------
                                                                   Increase/
                                                   February 14,     Decrease
  Mineral Resource Update    October 1, 2012         2012(i)          Oz Au 
----------------------------------------------------------------------------
----------------------------------------------------------------------------
                            Tonnes  Grade       Tonnes  Grade               
                            (Mill-     (g   Au  (Mill-     (g   Au          
                             ions)  Au/t)  kOz   ions)  Au/t)  kOz          
----------------------------------------------------------------------------
Totals           Indicated    12.4   1.48  590     5.5   1.65  290     +102%
              --------------------------------------------------------------
                  Inferred     8.2   2.07  548    13.2   1.73  740      -26%
----------------------------------------------------------------------------
Within                                                                      
 Potential                                                                  
 Pit                                                                        
 Constraining                                                               
 Shell           Indicated    10.6   1.24  422     4.0   1.11  140     +199%
              --------------------------------------------------------------
                  Inferred     6.5   1.91  397    11.2   1.57  570      -30%
----------------------------------------------------------------------------
Below                                                                       
 Constraining                                                               
 Shell           Indicated     1.7   2.99  168     1.5   3.04  150      +11%
              --------------------------------------------------------------
                  Inferred     2.0   2.62  151     2.0   2.65  170      -11%
----------------------------------------------------------------------------
----------------------------------------------------------------------------
    (i)  Full Mineral Resource information found in press release issued    
                 February 14, 2012 and at www.castillian.ca.                



Dr. Bill Pearson, P.Geo., President & CEO of Castillian, stated: "We are
delighted with the results of this mineral resource update, which was
accomplished with a limited, but highly targeted, drilling program. Our
technical understanding of the deposit continues to grow and the mineral
resources remain open along strike and downdip. Recent field work has outlined a
promising target zone just 150 metres north of the Mine Zone. In addition, there
is excellent potential to outline new zones along the more than eight kilometres
of underexplored mineralized structure that has been identified to date." Dr.
Pearson continued: "We have completed detailed planning for the next phase of
diamond drilling and have two diamond drills already onsite." 


The mineral resource estimates are presented in Table 3 below at different
cut-off grades to demonstrate the sensitivity of the mineral resources to change
in grade.




 Table 3: Mineral Resource Estimates at Different Cut-off Grades, Hope Brook
                                 Gold Project                               
                                                                            
--------------------------------------------------                          
             Within Constraining Shell                                      
----------------------------------------------------------------------------
                          Cut-off          Tonnes         Gold         Gold
                            Grade      (millions)        (g/t)         (Oz)
----------------------------------------------------------------------------
                 greater than 1.0             5.3        1.758      300,000
          ------------------------------------------------------------------
                 greater than 0.7             7.9        1.453      371,000
          ------------------------------------------------------------------
Indicated        greater than 0.5            10.6        1.236      422,000
          ------------------------------------------------------------------
                 greater than 0.4            12.9        1.099      454,000
          ------------------------------------------------------------------
                 greater than 0.3            16.4        0.936      493,000
----------------------------------------------------------------------------
                 greater than 1.0             4.9        2.277      361,000
          ------------------------------------------------------------------
                 greater than 0.7             5.8        2.066      384,000
          ------------------------------------------------------------------
Inferred         greater than 0.5             6.5        1.913      397,000
          ------------------------------------------------------------------
                 greater than 0.4             6.8        1.831      403,000
          ------------------------------------------------------------------
                 greater than 0.3             7.3        1.742      408,000
----------------------------------------------------------------------------
                                                                            
---------------------------------------------------                         
Below Constraining Shell                                                    
----------------------------------------------------------------------------
                          Cut-off          Tonnes         Gold         Gold
                            Grade      (millions)        (g/t)         (Oz)
----------------------------------------------------------------------------
                 greater than 4.0             0.3        4.721       42,000
          ------------------------------------------------------------------
                 greater than 3.0             0.6        3.997       83,000
          ------------------------------------------------------------------
Indicated        greater than 2.0             1.7        2.991      168,000
          ------------------------------------------------------------------
                 greater than 1.5             2.9        2.489      232,000
          ------------------------------------------------------------------
                 greater than 1.0             4.9        1.960      311,000
----------------------------------------------------------------------------
                 greater than 4.0             0.1        4.703       23,000
          ------------------------------------------------------------------
                 greater than 3.0             0.3        4.035       39,000
          ------------------------------------------------------------------
Inferred         greater than 2.0             1.8        2.624      151,000
          ------------------------------------------------------------------
                 greater than 1.5             2.5        2.375      194,000
          ------------------------------------------------------------------
                 greater than 1.0             3.4        2.074      230,000
----------------------------------------------------------------------------



The updated mineral resource is based on 646 diamond drill holes totaling
129,264 metres of historic and recent drilling. This includes 105 surface
diamond drill holes totaling 32,265 metres completed by Castillian from
September 2010 to June 2012. Mineral Resources have been estimated within a
constraining pit shell at a cut-off grade of 0.50 g Au/t and below this shell at
a cut-off grade of 2.0 g Au/t. Details on the mineral resource estimation
procedures are given in the notes below. An updated NI 43-101 Technical Report
on Hope Brook outlining the procedures for estimation of the mineral resource
estimates presented herein will be filed on SEDAR within 45 days of the date of
this press release. 


NOTES ON MINERAL RESOURCE ESTIMATION METHODOLOGY:



1.  Mineral resources are estimated in conformance with the CIM Mineral
    Resource definitions referred to in NI 43-101 Standards of Disclosure
    for Mineral Projects. Pierre Desautels, P.Eng., Principal Resource
    Geologist, and Jay Melnyk, P.Eng., Principal Mining Engineer, both of
    AGP Mining Consultants and Qualified Persons under NI 43-101 who are
    independent of the Company, have prepared and authorized the release of
    the mineral resource estimates presented herein. The Castillian and
    historical diamond drill hole databases and geological model developed
    by Castillian were reviewed and validated by Michael Cullen, P.Geo., of
    Mercator Geological Services, a Qualified Person as defined under NI 43-
    101 who is independent of the Company. This mineral resource estimate is
    an update of the first NI 43-101 mineral resource estimate released by
    the Company on February 14, 2012 (see press release February 14, 2012). 
    
2.  Specific gravities were determined by Castillian for a representative
    number of rock and mineralization types using industry standard methods.
    A total of 1,387 determinations exist in the database. The average value
    for each modeled domain was applied to the block model. Specific
    gravities were further confirmed in testing of representative core
    samples by G&T Metallurgical Services, a division of ALS Metallurgy. 
    
3.  Detailed geological logging and sectional interpretations by Castillian
    led to the development of three-dimensional (3D) domain models based
    mainly on lithological controls and partially on assay results. The
    wireframing resulted in a high grade envelope (approximately 2.0 g Au/t
    cut-off grade) within a lower grade silicic domain (approximately 0.5 g
    Au/t cut-off grade) that encompasses the bulk of the mineralization.
    These domains were utilized in the variography studies and in grade
    interpolation constraints. A footwall pyrite domain and a hanging wall
    argillic alteration domain were also wireframed to enable interpolation
    of local areas of mineralization and to provide possible exploration
    targets. The mineralization is cut by a series of mafic dikes that could
    not be individually wireframed, therefore a statistically derived dike
    model was constructed that was calibrated with available surface and
    historical underground geological information. The model prepared for
    the February 14, 2012 resource estimate was updated based on the new
    2012 diamond drilling information. 
    
4.  For the treatment of outliers each statistical domain was evaluated
    separately for gold and a combination of grade capping and search
    restrictions imposed on threshold values was used to restrict the
    influence of outliers. Capping only affected a small number of samples. 
    
5.  The composite intervals selected were 2.5 metres. Grade capping was
    applied prior to compositing. 
    
6.  A 3D geological block model was generated using GEMS(C) software. The
    block model matrix size is 15 metres x 5 metres x 10 metres. Ordinary
    kriging was used for all domains with inverse distance and nearest
    neighbour check models. The interpolation was carried out in multiple
    passes with increasing search ellipsoid dimensions. Classification for
    all models was based primarily on the pass number followed by an
    adjustment to the class model, based on the distance to the closest
    sample and kriged variance. The area in the model where historical mine
    workings exist was downgraded to inferred due to uncertainties about the
    location and extent of these workings. Confirmation of the historical
    stope location by 2012 Castillian drilling allowed the selection of
    blocks eligible for downgrading to be constrained to the immediate area
    surrounding the three dimensional modelled stopes. Insufficient data for
    copper was available in historical drill holes to allow for
    interpolation of copper grades in the model and therefore the total
    contained copper was omitted from this release. 
    
7.  The reported mineral resources are considered to have reasonable
    prospects of economic extraction. A Lerchs Grossman optimized
    constraining shell was generated to constrain the potential open pit
    material. This shell was designed using design parameters and costs for
    comparable deposits, 86% recovery based on new metallurgical testing and
    historical plant performance and a gold price of US$1,400 per ounce
    which is equivalent to the three year moving average price. The
    constraining shell extends down to the 4,800 metre level, the deepest
    level developed in the historical mine at approximately 340 metres below
    surface. 
    
8.  The rounding of tonnes as required by NI 43-101 reporting guidelines may
    result in apparent differences between tonnes, grade and contained
    ounces. 
    
9.  Mineral resources that are not mineral reserves do not have demonstrated
    economic viability. The estimate of mineral resources may be materially
    affected by environmental, permitting, legal, title, taxation,
    sociopolitical, marketing, or other relevant issues. 
    
10. The quantity and grade of reported inferred mineral resources in this
    estimation are uncertain in nature and there has been insufficient
    exploration to define these inferred mineral resources as indicated or
    measured mineral resources and it is uncertain if further exploration
    will result in upgrading them to indicated or measured mineral
    resources. 



SAMPLING, ASSAYING AND QUALITY CONTROL 

All drill core in the Castillian diamond drilling program (NQ (47.6 mm), BQTK
(40.6mm) and BQ (36.4mm)) was logged, photographed and then sawn in half with
one-half sent to the laboratory for analysis and the other half retained and
stored on site. All core samples were prepared and assayed at ALS Chemex, with
sample preparation done in Sudbury and analytical work done in Vancouver. All
locations of ALS Chemex are ISO 9001:2000 certified. The entire sample received
is weighed and crushed to greater than or equal to 70% passing 2mm (10 mesh). A
sample split of up to 1000g is then pulverized to greater than or equal to 85%
passing 75 microns (200 mesh) to produce a homogenized sample. A 50g aliquot is
used for fire assaying with an atomic absorption (AA) finish to determine gold
concentration. Copper is initially analyzed using a four acid digestion ICP
(inductively coupled plasma-atomic emission spectrometry) method. Any results
for copper greater than 10,000 ppm are assayed further by a four acid digestion
and "ore grade" ICP method. Internal quality control includes the use of blanks,
duplicates and standards in every batch of samples. The Company also conducts
internal check assaying using certified external reference standards and blanks.
Regular external check assays are performed at a second certified Canadian
commercial laboratory. Castillian also inserts external reference standards as
well as blank granite drill core in each sample batch as a further external
check.


QUALIFIED PERSONS 

Dr. Bill Pearson, P.Geo., President and CEO of Castillian, who is a qualified
person as defined by NI 43-101, has reviewed and approved the scientific and
technical content of this press release. Pierre Desautels, P.Eng., Principal
Resource Geologist, and Jay Melnyk, P.Eng., Principal Mining Engineer, both of
AGP Mining Consultants and Qualified Persons under NI 43-101 who are independent
of the Company, have prepared and authorized the release of the mineral resource
estimates presented herein. The Castillian and historical diamond drill hole
databases and geological model developed by Castillian were reviewed and
validated by Michael Cullen, P.Geo., of Mercator Geological Services, a
Qualified Person as defined under NI 43-101 who is independent of the Company. 


ABOUT CASTILLIAN 

Castillian Resources Corp. is a Canadian mineral exploration company listed on
the TSX Venture Exchange under the symbol "CT" and on the OTCQX International
under the symbol "CTIIF" The Company has gold and base metal properties in
Canada and South America. Castillian's flag ship property is the Hope Brook Gold
Project located in southwestern Newfoundland, which has 590,000 ounces of NI
43-101 compliant indicated mineral resources and 548,000 ounces of inferred
mineral resources. Castillian has outlined an extensive new Gold-in-Soil anomaly
trend on its Canadian Creek property in the Yukon that is adjacent to Kaminak's
Sugar Gold-in-Soil trend.


Cautionary Note Regarding Forward-looking Information 

This press release contains "forward-looking information" within the meaning of
applicable Canadian securities legislation. Forward-looking information
includes, but is not limited to, statements regarding exploration prospects and
timing of future exploration. Generally, forward-looking information can be
identified by the use of forward-looking terminology such as "plans", "expects"
or "does not expect", "is expected", "budget", "scheduled", "estimates",
"forecasts", "intends", "anticipates" or "does not anticipate", or "believes",
or variations of such words and phrases or state that certain actions, events or
results "may", "could", "would", "might" or "will be taken", "occur" or "be
achieved". Forward-looking information is subject to known and unknown risks,
uncertainties and other factors that may cause the actual results, level of
activity, performance or achievements of the Company to be materially different
from those expressed or implied by such forward-looking information, including
but not limited to: general business, economic, competitive, political and
social uncertainties; the actual results of current exploration activities;
future prices of mineral prices; failure of plant, equipment or processes to
operate as anticipated; accidents, labour disputes and shortages and other risks
of the mining industry. Although the Company has attempted to identify important
factors that could cause actual results to differ materially from those
contained in forward-looking information, there may be other factors that cause
results not to be as anticipated, estimated or intended. There can be no
assurance that such information will prove to be accurate, as actual results and
future events could differ materially from those anticipated in such statements.
Accordingly, readers should not place undue reliance on forward-looking
information. The Company does not undertake to update any forward-looking
information, except in accordance with applicable securities laws.


Information Concerning Estimates of Indicated and Inferred Resources 

This news release uses the terms "indicated resources" and "inferred resources".
Castillian advises investors that although these terms are recognized and
required by Canadian regulations (under NI 43-101), the U.S. Securities and
Exchange Commission does not recognize them. Investors are cautioned not to
assume that any part or all of the mineral deposits in these categories will
ever be converted into mineral reserves. In addition, inferred resources have a
great amount of uncertainty as to their existence, and economic and legal
feasibility. It cannot be assumed that all or any part of an inferred mineral
resource will ever be upgraded to a higher category. Under Canadian rules,
estimates of inferred mineral resources may not form the basis of feasibility or
pre-feasibility studies, or economic studies except for preliminary economic
assessments as defined under NI 43-101. Investors are cautioned not to assume
that part or all of an inferred resource exists, or is economically or legally
mineable.


To view Figure 1, please visit the following link:
http://media3.marketwire.com/docs/ct1001fig1.pdf.


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